/ News

18.10.2012

Researchers create 'nanoflowers' for energy storage, solar cells

Researchers from North Carolina State University have created flower-like structures out of germanium sulfide (GeS) – a semiconductor material – that have extremely thin petals with an enormous surface area. The GeS flower holds promise for next-generation energy storage devices and solar cells.

"Creating these GeS nanoflowers is exciting because it gives us a huge surface area in a small amount of space," says Dr. Linyou Cao, an assistant professor of materials science and engineering at NC State and co-author of a paper on the research.

"This could significantly increase the capacity of lithium-ion batteries, for instance, since the thinner structure with larger surface area can hold more lithium ions. By the same token, this GeS flower structure could lead to increased capacity for supercapacitors, which are also used for energy storage." To create the flower structures, researchers first heat GeS powder in a furnace until it begins to vaporize.

The vapor is then blown into a cooler region of the furnace, where the GeS settles out of the air into a layered sheet that is only 20 to 30 nanometers thick, and up to 100 micrometers long. As additional layers are added, the sheets branch out from one another, creating a floral pattern similar to a marigold or carnation.

"To get this structure, it is very important to control the flow of the GeS vapor," Cao says, "so that it has time to spread out in layers, rather than aggregating into clumps." GeS is similar to materials such as graphite, which settle into neat layers or sheets.

However, GeS is very different from graphite in that its atomic structure makes it very good at absorbing solar energy and converting it into useable power. This makes it attractive for use in solar cells, particularly since GeS is relatively inexpensive and non-toxic. Many of the materials currently used in solar cells are both expensive and extremely toxic.

Abstract

We report a synthesis of single crystalline two-dimensional (2D) GeS nanosheets using vapor deposition processes, and show that the growth behavior of the nanosheet is substantially different from those of other nanomaterials and thin films grown by vapor depositions.

The nanosheet growth is subject to strong influences of the diffusion of source materials through the boundary layer of gas flows. This boundary layer diffusion is found to be the rate-determining step of the growth under typical experimental conditions, evidenced by a substantial dependence of the nanosheet's size on diffusion fluxes.

We also find that high quality GeS nanosheets can only grow in the diffusion-limited regime, as the crystalline quality substantially deteriorates when the rate-determining step is changed away from the boundary layer diffusion. We establish a simple model to analyze the diffusion dynamics in experiments. Our analysis uncovers an intuitive correlation of diffusion flux with the partial pressure of source materials, the flow rate of carrier gas, and the total pressure in synthetic setup.

The observed significant role of boundary layer diffusions in the growth is unique for nanosheets. It may be correlated to the high growth rate of GeS nanosheets, ~3-5 [micrometer]/min, which is one order of magnitude higher than other nanomaterials (such as nanowires) and thin films.

This fundamental understanding on the effect of boundary layer diffusions may generally apply to other chalcogenide nanosheets that can grow rapidly. It can provide useful guidance for the development of general paradigms to control the synthesis of nanosheets.

Source: http://phys.org/news/2012-10-nanoflowers-energy-storage-solar-cells.html




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Founded by Russian entrepreneur Dmitry Itskov in February 2011 with the participation of leading Russian specialists in the field of neural interfaces, robotics, artificial organs and systems.

The main goals of the 2045 Initiative: the creation and realization of a new strategy for the development of humanity which meets global civilization challenges; the creation of optimale conditions promoting the spiritual enlightenment of humanity; and the realization of a new futuristic reality based on 5 principles: high spirituality, high culture, high ethics, high science and high technologies. 

The main science mega-project of the 2045 Initiative aims to create technologies enabling the transfer of a individual’s personality to a more advanced non-biological carrier, and extending life, including to the point of immortality. We devote particular attention to enabling the fullest possible dialogue between the world’s major spiritual traditions, science and society.

A large-scale transformation of humanity, comparable to some of the major spiritual and sci-tech revolutions in history, will require a new strategy. We believe this to be necessary to overcome existing crises, which threaten our planetary habitat and the continued existence of humanity as a species. With the 2045 Initiative, we hope to realize a new strategy for humanity's development, and in so doing, create a more productive, fulfilling, and satisfying future.

The "2045" team is working towards creating an international research center where leading scientists will be engaged in research and development in the fields of anthropomorphic robotics, living systems modeling and brain and consciousness modeling with the goal of transferring one’s individual consciousness to an artificial carrier and achieving cybernetic immortality.

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2015-2020

The emergence and widespread use of affordable android "avatars" controlled by a "brain-computer" interface. Coupled with related technologies “avatars’ will give people a number of new features: ability to work in dangerous environments, perform rescue operations, travel in extreme situations etc.
Avatar components will be used in medicine for the rehabilitation of fully or partially disabled patients giving them prosthetic limbs or recover lost senses.

2020-2025

Creation of an autonomous life-support system for the human brain linked to a robot, ‘avatar’, will save people whose body is completely worn out or irreversibly damaged. Any patient with an intact brain will be able to return to a fully functioning  bodily life. Such technologies will  greatly enlarge  the possibility of hybrid bio-electronic devices, thus creating a new IT revolution and will make  all  kinds of superimpositions of electronic and biological systems possible.

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This is the time when substance-independent minds will receive new bodies with capacities far exceeding those of ordinary humans. A new era for humanity will arrive!  Changes will occur in all spheres of human activity – energy generation, transportation, politics, medicine, psychology, sciences, and so on.

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